NPK fertilizers, which supply the three essential macronutrients—Nitrogen (N), Phosphorus (P), and Potassium (K)—to support plant growth, are formulated using a diverse range of raw materials. These materials are primarily derived from two major sources: industrial synthesis, which is the main route for nitrogen production, and mineral mining, the primary source for phosphorus and potassium. Additionally, manufacturers incorporate various additives and fillers to refine the fertilizer’s properties. Understanding these raw materials is key to grasping how NPK fertilizers are manufactured and tailored to meet different agricultural needs.
Nitrogen, a critical nutrient for foliage growth, is uniquely sourced through industrial synthesis rather than mining. The cornerstone of nitrogen production is the Haber-Bosch process, which extracts nitrogen gas from the air and combines it with hydrogen (typically derived from natural gas) to produce ammonia. Ammonia serves as the fundamental building block for all major nitrogen-rich raw materials. Urea, the most widely used high-nitrogen source (containing 46% nitrogen), is created by reacting ammonia with carbon dioxide. Ammonium salts, including ammonium nitrate, ammonium sulfate, and ammonium chloride, are another class of nitrogen sources derived from ammonia. Calcium nitrate, valued for its high solubility, is also produced using ammonia as a key raw material, making it suitable for crops requiring quick nitrogen uptake.